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5-苯基-1,3,4-噻二唑/噁二唑-2-硫基乙酸铜配合物的合成及其晶体结构
  • 摘要

    合成了新的2个双核铜配合物,经元素分析、红外光谱和X-射线单晶衍射对其结构进行表征.配合物A(分子式C44H44Cu2N8O16S4,Mr = 1 196.25),属于三斜晶系,空间群P-1,晶胞参数a = 8.389 3(14),b = 11.580(2),c = 13.919(2)(A),β= 91.717(2)°,Z = 1,V = 1 263.6(4)(A),Dc = 1.572 g/cm3,μ = 1.084 mm-1,F(000) = 614,R1 = 0.050 9,wR2 = 0.140 6.配合物B(分子式C42H40Cu2N8O12S8,Mr = 1 232.48),属于单斜晶系,空间群P2(1)/c,晶胞参数a = 8.955 7(13),b = 9.781 4(14),c = 28.914(4)(A),β= 95.419(2)°,Z = 2,V = 2 521.6(6)(A)3,Dc=1.623 g/cm3,μ=1.243 mm-1,F(000) = 1 260.0,R1= 0.040 2,wR2 = 0.104 2.

  • 作者

    安悦  郭志萍  张婷  魏魏  邢颖  AN Yue  GUO Zhi-ping  ZHANG Ting  WEI Wei  XING Ying 

  • 作者单位

    辽宁师范大学,化学化工学院,辽宁,大连,116029/沈阳化工研究院,染料室,辽宁,沈阳,110021

  • 刊期

    2010年1期 ISTIC

  • 关键词

    1,3,4-噻二唑  合成  1,3,4-噁二唑  晶体结构 

参考文献
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  • [2] 孙乐,褚长虎,张自义. 5-取代1,3,4-噁二唑-2-硫基乙酸的合成. 甘肃科学学报, 1998,4
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