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综合馆
聚合物分子刷的合成与应用
  • 摘要

    本文综述了近年来在线形聚合物、树枝状大分子及树枝化聚合物等不同聚合物的每个重复单元上,高密度地、通过不同联接方式接枝上新的聚合物侧链而形成的刷形接枝共聚物,即聚合物分子刷的研究进展.主要介绍聚合物分子刷的三种合成途径,即"大单体聚合法","从主链接枝法"及"接枝到主链法",并对不同路线的特点进行分析,同时对分子刷在制备纳米杂化材料、纳米导线及智能材料等方面的应用进行了综述.

  • 作者

    张磊  李文  张阿方  Zhang Lei  Li Wen  Zhang Afang 

  • 作者单位

    郑州大学材料科学与工程学院,郑州,450052

  • 刊期

    2006年7期 ISTIC SCI PKU

  • 关键词

    分子刷  聚合反应  可控自由基聚合  树枝状大分子 

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